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Acids and Bases: Together again!

Author: Wilma Amaro



Time: One class period, Week 3
Preparation
Time:
Approximately 1hour
Materials: Board, dry erase markers or chalk; 500ml-graduated cylinder, approximately 500ml of 1M, NaOH and 500ml, 1M HCl, phenolphthalein and methyl red indicators, distilled water, balance, beakers, funnels, droppers, glass stirrers, funnels, wash bottles.

Abstract

Many chemical compounds are produced as industrial waste and discarded into the air and water. Understanding the physical and chemical properties of compounds (i.e. pH) allows the development of simple detection methods. This lesson is designed to engage students in the topic of acid-base reactions. At this point, students should have an understanding of molecular and structural formulas, atomic and molecular weights, the mole, and concentration (specifically in terms of molarity.) They should also have been exposed to the concept of chemical reactions.

Objectives

Students will be able to:
1. Identify principles behind acid-base reactions
2. Predict factors that may affect an acid-base reaction

National Science Education Standard

Content Standard A: Inquiry
* Identify questions and concepts that guide scientific investigations
* Formulate and revise scientific explanations and models using logic and evidence

Content Standard B: Physical Science
* Structure and properties of matter reactions
* Chemical reactions

Content Standard F: Science in Personal and Social Perspectives
* Personal and community health
* Environmental quality
* Natural and human-induced hazards

Teacher Background

Strong acids (having a pH of 2 or less) and strong bases (having a pH of 12.5 or greater) are considered corrosive. Products with these properties are often generated in association with businesses such as vehicle maintenance and dismantling, printing, photo finishing labs, surface coating, metal finishing electronics, computers, and educational institutions.

The release of products with such properties can often result in a threat to human health and the environment.

Preventing disease involves understanding the cause of an illness and changing the conditions that permit it to occur. When chemicals are implicated, this is usually done by trying to minimize or eliminate the chemical in the environment or by minimizing the adverse effects of chemicals found in the environment and food supply (NIEHS, 2000). One of the environmental resources that need to be monitored closely is water. Water can be analyzed for acid/base content by doing titrations.

Related and Resource Websites

http://www.chemistrycoach.com/acids.htm
Review of fundamental concepts in acid/base reactions. Includes a discussion on electrolytes.

http://chemed.chem.purdue.edu/genchem/topicreview/bp/ch11/acidbaseframe.html
Review of acid/base definitions.

http://members.aol.com/logan20/ionic_eq.html
Acid/base equilibrium.

http://www.flinnsci.com/Documents/ProductPDFs/ChemTopicLabs/vol%2013/Demo_Summaries_Concept_vol13.pdf Acid/base demonstrations

http://www.dec.state.ny.us/website/ppu/ecppsqg.pdf
EPA regulations for small businesses

http://www.chemguide.co.uk/physical/acidbaseeqia/indicators.html
Theoretical background on indicators

http://qldscienceteachers.tripod.com/junior/chem/acid.html

Examples of bases and acids; includes examples of indicators and the pH range they detect

http://classes.aces.uiuc.edu/ACES100/Mind/CMap.html
Information about concept maps. Includes different types

 

Activity

Materials, for teacher:
Two beakers, any size
Triple-beam or any kind of balance
Glass stirrer
NaOH pellets
Two 1-L volumetric flasks
HCl, 15 M (molarity is commonly found on liquid reagent bottles. HCl is usually 15M when purchased through chemical supply companies. Some local companies may be able to prepare solutions of a specific molarity for a fee)
Funnel
Droppers
Wash bottle
Teacher prep:
Solution preparation:

CAUTION: Wear goggles, apron and rubber gloves when preparing these solutions. HCl solution must be prepared under a hood.

NaOH
Weigh 40.0g of NaOH in a beaker, add enough distilled water to dissolve it; do not add more than 200 or 300 ml. Transfer to 1-L volumetric flask using a funnel and wash bottle. Bring water level up to the 1-liter mark on the neck of the flask using a dropper. Label flasks clearly with NaOH, 1M, include date.

HCl
Measure 15ml of 15M HCl using a pipette and transfer into 1-L volumetric flask. Bring water level up to the 1-liter mark on the neck of the flask using a dropper. Label flask clearly with HCl 1M, include date.

Class Demo:

1. Ask each student to generate a list of 15-20 words/ideas they relate to chemical reactions. Organize these into a concept or mind map.


2. In a 500mL-graduated cylinder, pour about 200mL of 1M NaOH. Add three or four drops of phenolphthalein. Gradually add 1M HCl, until the pink color disappears. The color change of phenolphthalein from pink to clear indicates an acidic solution. Use 1M NaOH to bring the color back to pink and then add more 1M HCl to make a clear solution again. Do this a few times. Write out the formula for HCl and NaOH, on the board.

3. Ask students to pair up and come up with an explanation for what they saw. Have them speculate about the reactants, concentration and what it takes for the color to change.


4. Add three or four drops of methyl red indicator to the mixture used in steps 1 and 2 above, and gradually add 1M NaOH until the color of the solution changes from red to yellow. The color change to yellow indicates that the solution now has a basic pH.


5. Repeat steps 1-3 a couple of times so students can see how the reaction goes back and forth, noting the color change. Have students make predictions about the color change (Will it turn pink, red, etc.?) as the demonstration progresses. Identify HCl and NaOH as an acid and a base.

Class discussion

6. Start asking students: “What happens between HCl and NaOH?”, “Why do acids and bases matter to us?”, “What are some acids and bases used at home?”, “How do we discard them?”. Present facts about production of acids and bases by local businesses using provided teacher background. Ask students if they live, or know anyone, who lives near one of these businesses.

7. Have students add more terms on their concept maps this time using the demo and including class discussion.

Closure
Students will exchange their concept maps with a classmate. They will write down three main ideas represented on their classmate’s concept map on a separate piece of paper. Teacher will ask students to volunteer some of the ideas.

Homework
Find three examples of acids and three examples of bases commonly used at home. Determine how each is discarded. Answer the question: “What actually happens to them?”

Embedded Assessment
The lesson will be assessed using the concept map. Collect and save concept maps for future reference.

 

 

 


PULSE is a project of the Community Outreach and Education Program of the Southwest Environmental Health Sciences Center and is funded by:


an
NIH/NCRR award #16260-01A1
The Community Outreach and Education Program is part of the Southwest Environmental Health Sciences Center: an NIEHS Award

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Supported by NIEHS grant # ES06694


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